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排序方式: 共有2743条查询结果,搜索用时 15 毫秒
1.
Yuanyuan Chen Jian Peng Tian Sheng Ruixuan Qin Shuqi Dai Zaifa Shi Zichao Tang Laisen Wang Qinghua Zhang Bin Han Liping Sun Jun Xu Jian Weng 《Advanced functional materials》2021,31(42):2104246
Radicals are closely related to human life and health and have been widely used in biology, chemistry, functional materials, etc. However, the high reactivity, disorder, and short half-lives limit their wide applications. Therefore, it remains a great challenge to prepare stable and ordered radicals. Herein, radicals are prepared with protective umbrellas (diethylmethyleneamine, DEMA) that are integrated on the surface of 2D layered materials to isolate water and oxygen and enhance the stability of radicals. Taking 2D black phosphorus (BP) as an example: triethylamine reacts with dichloromethane to form quaternary ammonium salts with further Hoffmann elimination to produce DEMA radicals that could react with one electron of a lone pair electrons in P on the surface of BP to produce P radicals, which shows a prolonged half-life of 21 days at room temperature. First-principle calculations and electron paramagnetic resonance fitting confirm that the steric hindrance constructed by dense DEMA passivation layer acts as a protective umbrella and the 2D coupling of P radicals and other P atoms in 2D BP plane to enhance the stability and strong superexchange interaction of P radicals. Furthermore, it is a general strategy to produce stable radicals integrated on the 2D plane. 相似文献
2.
Feng Yingrui Hu Kang Zhang Min Ding Wei Kong Xiangkai Sheng Zhigao Liu Qiangchun 《Journal of Materials Science》2022,57(1):204-216
Journal of Materials Science - Rationally designing microwave absorption materials with highly efficient and tunable bandwidth is in great demand but remains a huge challenge. In this study,... 相似文献
3.
Lvlv Gao Cuiping Gu Jingjuan Zhao Xinjie Song Jiarui Huang 《Ceramics International》2019,45(3):3425-3434
Manganese monoxide (MnO) nanowire@reduced graphene oxide (rGO) nanocomposites are synthesized using a simple hydrothermal method combined with a calcination process. The structural and morphological characterization of the composites indicates that the MnO nanowires homogeneously anchor on both sides of the cross-linked rGO. The nanocomposites exhibit a high surface area of 126.5?m2 g?1. When employed as an anode material for lithium-ion batteries, the nanocomposites exhibit a reversible capacity of 1195 mAh g?1 at a current density of 0.1?A?g?1, with a high charge-discharge efficiency of 99.2% after 150 cycles. The three-dimensional architecture of the present materials exhibits high porosity and electron conductivity, significantly shortening the diffusion path of lithium ions and accelerating their reaction with the electrolyte, which greatly improves the lithium-ion storage properties. These excellent electrochemical performances make the composite a promising electrode material for lithium-ion batteries. 相似文献
4.
Ziwen Wu Tianping Zhang 《International Journal of Adaptive Control and Signal Processing》2021,35(9):1768-1788
In this article, the issue of adaptive finite-time dynamic surface control (DSC) is discussed for a class of parameterized nonlinear systems with full state constraints. Using the property of logarithmic function, a one-to-one nonlinear mapping is constructed to transform a constrained system into an unconstrained system with the same structure. The nonlinear filter is constructed to replace the first-order linear filter in the traditional DSC, and the demand on the filter time constant is reduced. Based on finite-time stable theory and using modified DSC, the finite-time controller is designed via DSC. Theoretical analysis shows that all the signals in the closed-loop system are semiglobal practical finite-time stable. Furthermore, none of the states are outside the defined open set. In the end, simulation results are presented to demonstrate the effectiveness of the proposed control schemes with both linear filters and nonlinear filters. 相似文献
5.
6.
《Ceramics International》2022,48(1):811-823
Polyaniline (PANI)-based networks combined with Fe3O4 hollow spheres and carbon balls (FCP) for improved electromagnetic wave (EMW) absorption were investigated using an easy-to-industrialize solvothermal and physical method. Hollow structure Fe3O4 spheres with a lower density than that of the common solid sphere were prepared. As a thin and light magnetic material, Fe3O4 hollow spheres generate magnetic loss, carbon balls and PANI networks generate dielectric loss. The magnetic and conductive parts play appropriate roles in achieving complementarity in the EMW absorption. The relatively high specific surface area introduced by PANI networks promotes interfacial polarization and further supports dielectric loss. In conclusion, the above reasons provide multiple attenuation mechanisms. Samples FCP1 (?65.109 dB, at 12.800 GHz, 1.966 mm, from 5.6 to 18.0 GHz) and FCP2 (?61.033 dB, at 8.480 GHz, 3.328 mm, from 4.3 to 18.0 GHz) demonstrated a wide bandwidth, a small thickness, a minimum reflection loss (RL), and a low loading ratio (25%) in paraffin-based composites. Specifically, their loading ration of 25% is much lower than the loading ratio of conventional materials (usually 50% and above). In addition, the bandwidth is excessively wide, above 12 GHz, possessing good absorption performance in continuous intervals with different thicknesses. Such excellent characteristics have rarely been reported in literature. 相似文献
7.
为解决证据组合规则中一票否决和弱决策证据在低冲突情况下出现的反直观推理的现象,提出一种有效折扣证据源的冲突证据合成方法。首先根据证据的信任函数和似然函数求得证据间的相似度,然后求出证据之间的支持程度,并确定折扣因子,最后采用Dempster组合规则合成利用折扣因子修正后的证据源。数值算例分析结果表明,改进后的证据组合方法可以有效地处理证据冲突。 相似文献
8.
Jing Li Ping Liu Yan Qu Tingdi Liao Bin Xiang 《International Journal of Hydrogen Energy》2018,43(5):2601-2609
The number of exposed active sites in a catalyst plays a key role in determining its catalytic performance. However, the aggregation effect in nanostructured catalysts causes much less reactive sites exposed. In this paper, we report a novel structure of WSe2/rGO with highly exposed WSe2 active edge sites by uniformly imbedding the rGO between each WSe2 nanosheets. With the introduction of rGO, the electron transport property of the WSe2/rGO hybrid structure has also been enhanced. The structure and composition of the samples were investigated by the X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. Our electrochemical characterizations confirm that the WSe2/rGO hybrid structure exhibits enhanced electrochemical catalytic performance with a Tafel slop of 85 mV/dec for HER, much smaller than that of the pure WSe2. 相似文献
9.
《Ceramics International》2020,46(14):22164-22170
For a long time, rare-earth ion-doped phosphors have been widely used in temperature sensing because of their excellent light-emitting properties. However, most of the rare earth elements are relatively rare and expensive, so the transition group elements that are economical and easy to obtain have been favored by researchers. This paper presents a new type of phosphor doped with rare earth ion and transition metal for optical temperature measurement. In recent years, Mn4+-doped phosphors have attracted wide attention because of their strong deep red light-emitting properties. La2LiSbO6 provides a good host environment for Mn4+ and Eu3+ due to its unique crystal structure. In this paper, a series of La2LiSbO6 phosphors singly doped with Mn4+ and Eu3+, and co-doped with Eu3+/Mn4+ were synthesized. The crystal phases and optical properties of these materials were characterized and analyzed in detail. We specifically studied the temperature dependence of the fluorescence intensity of the optimized La2LiSbO6: Eu3+, Mn4+ phosphors at 303K–523K. The experimental results prove that the thermal responses of Mn4+ and Eu3+ are different. With increasing temperature, the thermal quenching of the Mn4+ fluorescence intensity is much faster than that of Eu3+, so the temperature characteristics can be explored by the fluorescence intensity ratio (FIR) of Eu3+ to Mn4+. At 523 K, its maximum relative sensitivity and maximum absolute sensitivity can reach 0.891% K−1 and 0.000264 K-1, respectively. Our experimental analysis shows that La2LiSbO6:Eu3+/Mn4+ phosphors have relatively high temperature sensitivity and have potential application prospects in the field of high temperature sensing. 相似文献
10.
Yao Dajie Liu Xiaofei Wu Jian 《International Journal of Control, Automation and Systems》2020,18(9):2251-2258
International Journal of Control, Automation and Systems - In this paper, the tracking problem for a class of uncertain nonlinearly parameterized systems with input delay based the adaptive... 相似文献